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UPS measurements were done for probing only the outer surface of the system, utilizing the He II spectral line at Raman spectroscopy was performed on samples prepared in the same manner as for SEM. Spectra were recorded using a Witec alphaM confocal Raman microscope. The samples were irradiated with an excitation wavelength of The details of the used in situ cell were described elsewhere [47,48].

Experiments were done in 0. During the measurement, the pump rate was reduced to In this work, the duration of a single ellipsometric measurement was ca. Several analysis methods have been tested on the resulting data, as described previously []. In total, three repetitions of the experiments have been carried out. Stratmann is acknowledged for continuous support. Mikalai V. Malashchonak, Alexander V. Mazanik, Olga V. Streltsov and Anatoly I. Twitter: BeilsteinInst.

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Please enable Javascript and Cookies to allow this site to work correctly! Mayrhofer 1,3 , Michael Rohwerder 1 and Andreas Erbe 1,4. Abdulrahman Altin. Maciej Krzywiecki. Adnan Sarfraz. Cigdem Toparli. Claudius Laska. Philipp Kerger. Aleksandar Zeradjanin.

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  5. Andreas Erbe. Results and Discussion. Lower values of E corr are an indication of a suppression of the cathodic process of oxygen reduction [16] , 1 E corr stablized quickly in the presence of the inhibitor, while reference measurements showed a slower decrease.


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    Corrosion and Electrochemistry of Zinc

    From EIS data, the corrosion current densities i corr were estimated as given on page 48 of [16] as 3 from the area-normalized polarization resistance R p. Supporting Information. Supporting Information File 1: Additional experimental data. Format: PDF Size: 3. Corrosion Protection by Inhibition. B , , — Passivity of Metals, Alloys, and Semiconductors. B , 79, Interfaces , 8, — Growth , , 58— B , 76, B , 77, Acta , , — Langmuir , 29, — Reference XPS Simplified.

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    Go to reference References 29, References 36, References 44, References 19,40, References 17, Browse All Figures Return to Figure. Previous Figure Next Figure. Email or Customer ID. Forgot password? Old Password. New Password.

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    Password Changed Successfully Your password has been changed. Returning user. Request Username Can't sign in? Forgot your username? Enter your email address below and we will send you your username. Indeed, aside from zinc's well-known attributes as an alloying element, its widespread use is principally due to its electrochemical properties, which include a well-placed position in the galvanic series for protecting iron and steel in natural aqueous environments and its reversible dissolution behavior in alkaline solutions. JavaScript is currently disabled, this site works much better if you enable JavaScript in your browser.

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